CeO2納米粒子催化魯米諾-過(guò)氧化氫的化學(xué)發(fā)光特性
中國(guó)測(cè)試雜志
石文兵
（長(zhǎng)江師范學(xué)院化學(xué)化工學(xué)院，重慶 涪陵 408100）
摘 要：在碳酸鹽緩沖溶液中，CeO2納米粒子催化魯米諾-H2O2發(fā)光體系表現(xiàn)出對(duì)pH、CeO2納米粒子放置時(shí)間和H2O2濃度依賴的特性。在pH 9.15~11.48時(shí)為抑制發(fā)光，在pH 11.68~11.90為增敏發(fā)光；新鮮制備的納米粒子表現(xiàn)兩種催化效果（抑制或增敏），放置24 h后的納米粒子均表現(xiàn)增敏效果；在H2O2濃度較低時(shí)為抑制發(fā)光，在H2O2濃度較高時(shí)為增敏發(fā)光。初步提出了這一催化特性受CeO2納米粒子中Ce3+和Ce4+兩種價(jià)態(tài)調(diào)控的假設(shè)。
關(guān)鍵詞：化學(xué)發(fā)光；CeO2納米粒子；過(guò)氧化氫；魯米諾
中圖分類號(hào)：O482.31；O614.33+2；TB383；TM930.12 文獻(xiàn)標(biāo)志碼：A 文章編號(hào)：1674-5124（2013）03-0034-04
Chemiluminescent properties of Luminol-H2O2 catalyzed by CeO2 nanoparticles
SHI Wen-bing
（School of Chemisty and Chemical Engineering，Yangtze Normal University，F(xiàn)uling 408100，China）
Abstract: In carbonate buffer solution， the chemiluminescent properties of Luminol-H2O2 catalyzed by CeO2 nanoparticles has strong dependence on pH， CeO2 nanoparticles storage time and H2O2 dependence. In the range of pH 9.15-11.48， it showed chemiluminescence （CL） inhibition， however， in range of pH 11.68-11.90， it displayed CL enhancement. The performance of freshly prepared nanoparticles exhibited two catalytic effect （inhibition or enhancement）， and the nanoparticles stored for more than 24 h， shows sensitization effect. CL inhibition was obtained in low H2O2 concentration and CL enhancement could be observed in high H2O2 concentration. A preliminary hypothesis that the catalytic properties of CeO2 nanoparticles on luminol and H2O2 tuned by Ce3+ and Ce4+ valence state has been proposed in this paper.
Key words: chemiluminescence； CeO2 nanoparticles； H2O2； Luminol
